Journal of Chromatography & Separation Techniques
Open Access
ISSN: 2157-7064
+44 1300 500008
ISSN: 2157-7064
+44 1300 500008
Ravindra Singh
Indian Oil Corporation Limited,
Sector-13, Faridabad, Haryana
India
Research Article
Simultaneous Determination of Ammonium Ion, MDEA, Common Metal Cations and Dialkyl Amines in Amine Processing Solution by Ion Chromatography
Author(s): Ravindra Singh, Mohammad Ali Khan, Anil Yadav, Anju Chopra and Kagdiyal VRavindra Singh, Mohammad Ali Khan, Anil Yadav, Anju Chopra and Kagdiyal V
In the present study a new method has been developed for the separation and estimation of common metal cations (Li+, Na+, K+), Methyl diethanolamine (MDEA) (and types of alkyl amines) and their degradation products including ammonium ion used in amine processing solution. The acid treating amines such as dimethyl amine (DMA), Diethyl amine (DEA), Dipropylamine (DPA), Diisopropyl amine (DPA) and Dibutyl amine (DBA) in amine processing solution have been separated by Ion Chromatography (IC) using conductivity detector in single column mode. Desired separation was achieved within 20 min using mixture of 3 mM CH3SO3H+CH3CN (90:10) as mobile phase on Dionex Ion Pac SCS1 column at temperature of 30°C. Calibration curve for all the cations (Li+, Na+, K+, NH4+) in the c.. View More»
DOI:
10.4172/2157-7064.1000416