Journal of Chromatography & Separation Techniques
Open Access
ISSN: 2157-7064
ISSN: 2157-7064
Zeid Abdullah Alothman
King Saud University, Saudi Arabia
Posters & Accepted Abstracts: J Chromatogr Sep Tech
The research work was carried out to synthesize mesoporous materials based on MCM-41 with high surface areas, large pore sizes, narrow pore size distributions, and high thermal, hydrothermal, and mechanical stabilities. This was completed by following the same procedures reported for the fabrication of the MCM-41 but with alterations in the surfactants and the additives used, and the reaction conditions employed such as the pH, the temperature, and aging time. Moreover, the study aimed to modify such synthesized mesoporous materials with different functional groups of interest and evaluate their abilities in adsorption and separation of transition and heavy metal ions, and radioactive materials from aqueous medium. The functionalization of these mesoporous materials was done using different methods in order to maximize the number of groups on the surface and inside the pores. Different techniques such as infrared (IR), solid-state 29Si and 13C nuclear magnetic resonance (NMR), x-ray powder diffraction (XRD), thermal gravimetric analyses (TGA), and scanning and transmission electron microscopes (SEM and TEM) were used to confirm the production of the desired products. The surface area, pore size and pore size distribution were determined using the surface area analysis (BET) method. The surface properties (e.g., number of groups on the surface) of these materials were determined by the adsorption of a proper probing molecule. The adsorption and separation abilities of these modified materials for the transition and heavy metal ions, and radioactive materials in aqueous solution were performed in the pH range from 2 to 8 at room temperature. The equilibrium concentration of the metal ions were determined using lead analysis test kit for the lead and using ultraviolet-visible (UV-Vis), inductive couple plasma (ICP), and atomic absorption spectroscopy (AAS) for the rest of materials. The synthesized mesoporous materials possess high surface areas, large pore sizes, narrow pore size distributions, and high thermal, hydrothermal, and mechanical stabilities. The materials were found to have high selectivity and capacity in the adsorption and separation of the transition and heavy metal ions in the aqueous solution. In addition, they showed great selectivity and capacity for the adsorption and separation of the radioactive materials in aqueous medium.
E-mail: zaothman@ksu.edu.sa