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Journal of Chemical Engineering & Process Technology

Journal of Chemical Engineering & Process Technology
Open Access

ISSN: 2157-7048

+44-20-4587-4809

Obi C

Obi C

Rivers State
Nigeria

Publications
  • Research Article
    Batch Determination of Excess Molar Variables for Butanol and Acetonitrile Binary Mixtures
    Author(s): Okoye O and Obi COkoye O and Obi C

    In this study, the experimental excess molar enthalpy, entropy and excess molar Gibb’s free energy changes for the binary mixtures of butanol and acetonitrile have been measured at 345 K by means of a bomb calorimeter. The binary experimental excess molar enthalpy and Gibb’s free energy values were correlated by means of the Liebermann-Fried solution theory model equation. The result showed that Liebermann-Fried solution theory model was able to closely represent the experimental excess molar enthalpy and excess molar Gibb’s free energy data for the binary system with reasonable accuracy. The correlated and predicted results for all thermodynamic quantities measured have been drawn on a Table and plotted as well. The plots obtained revealed that the mixture has strong attractive forces and therefore deviate negatively from Raoult’s line. This deviation will str.. View More»
    DOI: 10.4172/2157-7048.1000391

    Abstract PDF

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