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Controllable preparation and application of squaraine containing | 47214
Organic Chemistry: Current Research

Organic Chemistry: Current Research
Open Access

ISSN: 2161-0401

Controllable preparation and application of squaraine containing nanometer hybrids with broad band absorption to near infrared by one step method


10th European Organic Chemistry Congress

March 21-22, 2019 | Rome, Italy

Nahla Omer, Fayin zhang, Gang Zhao, Shanyi Guang, Elwathig A M Hassan and Hongyao Xu

Donghua University, China

Posters & Accepted Abstracts: Organic Chem Curr Res

Abstract :

   Nowadays, organic dye materials have been receiving more interest in solar cell due to improved solution process ability, scalable synthesis, tunable chemical and physical properties via molecular design and low cost. However, the thermal stability, compatibility and aggregation of squaraine dye limited broad application. In this study, octavinyl-polyhedral oligomeric silsesquioxane OV-POSS has used to prevent all these problems. These are first time designed a novel hybrid large broad absorption ultra violet to near infrared transient absorption spectroscopy, prepared by OV-POSS with 6-Bromoquanaldine and Squaric acid (semisquaraine (SSQ), squaraine (SQ)). The systems were characterized by Fourier Transform Infrared Spectroscopy FTIR, 1HNMR, TGA, UV-Vis-Spectra, FESEM and DSC properties, and when a combination our system dyes with N719 as co-sensitization in photovoltaic performance using Ti foil-based solar cell DSSC the co-sensitization promote their light properties in our result due to the a broad spectral coverage in a big region from 400 to 800 nm. And showed the highest properties short circuit current density JSC of 20.09 mA cm-2 an open circuit voltage VOC of 0.74 V, fill factor FF 52.17% and power conversion efficiency PCE 7.73%, so exhibited good performance.

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