Journal of Chemical Engineering & Process Technology
Open Access
ISSN: 2157-7048
+44-20-4587-4809
ISSN: 2157-7048
+44-20-4587-4809
S.I.M.A.U., Department of Chemistry, Marche Polytechnic University, Brecce Bianche, Ancona, Italy
Research Article
Cellulose Acetate-Graft-Poly (Methyl Methacrylate): A “Graft from” Approach of Nitroxide Mediated Radical Polymerization
Author(s): Vernon Tebong Mbah*, Celli A, Cipolletti R, Sabbatini S and Stipa P
Poly (methyl methacrylate) was grafted onto cellulose acetate backbone using a “graft from” of Nitroxide Mediated Radical Polymerization (NMRP). The formation of cellulose acetate-co-poly (methyl methacrylate) using N-tert-butyl- N- (1-diethylphosphono-2,2-dimethylpropyl) (SG1)-nitroxide based macroalkoxyamine system was confirmed by FTIR and NMR analyses. The copolymer exhibited living characteristics as shown by NMR. DSC investigations showed a copolymer with a rich poly (methyl methacrylate) phase around 120°C and a rich cellulose acetate phase at around 175°C. .. View More»
DOI:
10.35248/2157-7048.20.11.399