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Separation of Cations from Nitric Acid Solutions Using Commercially Available Ion Exchange Resins
Journal of Chemical Engineering & Process Technology

Journal of Chemical Engineering & Process Technology
Open Access

ISSN: 2157-7048

Research Article - (2019)Volume 10, Issue 1

Separation of Cations from Nitric Acid Solutions Using Commercially Available Ion Exchange Resins

Gary Bond, Harry Eccles* and John D Emmott
 
*Correspondence: Harry Eccles, School of Physical Sciences and Computing, University of Central Lancashire, Preston PR1 2HE, UK, Tel: 01772893550, Email:

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Abstract

In a previous publication, the authors described a chromatographic process for the selective separation of fission products and minor actinides from uranium and plutonium in nitric acid solution. This paper has evaluated commercially available ion exchange materials for capacity, rate of uptake and selectivity for some fission products (inactive) and cerium (iii) and (iv) as surrogate for Pu and U. The fission products studied where Cs, Sr and Zr as these for various reasons present major challenges for the existing PUREX process and waste management. The commercial resins evaluated were various sulfonic acid, chelate ion exchangers and an undisclosed inorganic material all supplied by Purolite Ltd.

Keywords

Reprocessing; PUREX; Ion chromatographic separation; Cesium; Strontium; Commercial resins

Introduction

The potential for extractive chromatography as a replacement and/ or complementary reprocessing option to the PUREX process has been previously described [1]. UCLan’s process involves the separation of fission products and minor actinides from uranium and plutonium isotopes in 1 to 3 M nitric acid. This paper evaluates the potential of commercially available ion exchangers for the separation of Sr, Cs, Co and Zr ions from Ce (iii/iv) ions the surrogates for Pu and uranium [2]. These fission product cations were selected as:

1.Their chemistries and behaviour are different,

2.They account for a significant amount of β/γ activity present in spent fuel dissolver liquor,

3. Zr is responsible for significant challenges in the PUREX process [3].

Cerium ions (iii/iv) have been used as a surrogate for Pu in a variety of studies ranging from reprocessing, fuel fabrication to waste management [4]. The liquid-liquid extraction of cerium ions from nitrate solution using tri butyl phosphate was well established even before the conception of the PUREX process [5]. The Ce (iv) ion forms relatively weak nitrato complexes in nitric acid solution (~ 1 mole/l), with the Ce4+ ion predominating but with Ce (NO3)3+ and Ce (NO3)22+ ions increasing in stronger nitric acid [6].

Xe, Zr, Mo, Nd, Cs and Ru isotopes which are formed in the largest amounts in thermal fission, constitute about 70% of the fission product weight after a cooling time of ten years. Cesium and strontium and daughter isotopes account for about >90% of the total activity (Bq/t U) from fission products for 8-year cooled fuel, with a burn-up of 45 GWd/t (Table 1). At cooling times 10 to 1,000 years the activities of strontium-90 a strong β emitter with a half-life of 28.8 years and caesium-137 with a half-life of 30 years a strong β/γ emitter dominate among the fission products. They are the two most important fission products when considering reagent stability in a reprocessing flowsheet.

Radioisotope Bq/t U Heat rating factor (W/Bq) Heat rating contribution (W/tU)
Y-90 3.14E+15 1.50E-13 4.70E+02
Sr-90 3.14E+15 3.13E-14 9.84E+01
Rh-106 8.90E+13 2.60E-13 2.31E+01
Sb-125 4.65E+13 8.54E-14 3.97E+00
Cs-134 5.02E+14 2.75E-13 1.38E+02
Cs-137 4.38E+15 2.98E-14 1.31E+02
Ba-137 m 4.14E+15 1.06E-13 4.39E+02
Ce-144 3.33E+13 1.78E-14 5.92E-01
Pr-144 3.33E+13 1.98E-13 6.60E+00
Eu-154 1.72E+14 2.42E-13 4.16E+01
Am-241 7.65E+13 9.04E-13 6.91E+01
Cm-242 9.93E+09 9.95E-13 9.88E-03
Cm-244 1.21E+14 9.46E-13 1.14E+02
Total 1.53E+03

Table 1: Heat rating factor for some radioisotopes present in spent fuel dissolver liquor*.

Although the only important oxidation number for zirconium is +4, the solution chemistry is complicated as a number of ionic species can be present depending on the solution conditions. Zirconium ions can undergo extensive hydrolysis to produce colloidal species and polymerisation, which are pH and concentration dependent [7].

Although there is an abundance of metal extraction data for the selected commercial ion exchangers most if not all are restricted to slightly acid, neutral to alkaline pH regions far removed from 1 to 3 M acid [8]. The influence of pH (acidity) is known to influence both extraction and separation efficiencies; in addition metal speciation and hydrated ionic radii will be affected [9,10].

UCLan’s chromatography process relies on the sequential separation of individual radionuclides or families of radionuclides using appropriate stationary phases. The envisaged process will initially remove the comparative short-lived radionuclides such as Cs and Sr isotopes (significant β/γ emitters) thus reducing the radiation damage to downstream stationary phases (Figure 1) [11]. Reduction in radiation flux will allow organic exchangers to be considered for the subsequent separation of other radionuclides in later stages.

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Figure 1: UCLan’s Continuous chromatography separation process.

A major, if not the major separation consideration for the stationary phase will be the ability to achieve decontamination values (Df) comparable, if not better with those attained in the PUREX process for example 107 [12]. To achieve this figure would require the stationary phase to reduce say the Cs/Sr concentration from ~ 3 g/Kg U to ~ 0.3 μg/Kg U, based on the data in Tables 1 and 2 [8].

Radionuclide Approximate concentration
U ~300 g/l
Pu 3.6 g/l
Np 170 mg/l
Am 225 mg/l
Cm 8 mg/l
Alkali metals (Cs, Rb) 1.3 g/l
Alkaline earth metals (Sr and Ba) 1.05 g/l
Y and lanthanides 4.4 g/l
Zr 1.5 g/l
Se and Te 220 mg/l
Mo 1.4 g/l
Tc 350 mg/l
Ru, Rh, Pd 1.8 g/l
Ag, Cd, Sn. Sb 60 mg/l

Table 2: Dissolver liquor concentrations*.

The optioneering investigations reported in this paper are based on batch studies to identify candidate exchangers that will be further evaluated in column experiments. Some of the selected commercial ion exchangers exhibit good extraction efficiencies for copper; this metal was included in this study to provide a comparison between their intended commercial use and their performance in 1 to 3 M nitric acid conditions, i.e., benchmarking exercise [8,13].

Extraction efficiencies, separation factors and rate of cation uptake were calculated from equilibrium batch studies over a range of nitric acid molar strengths.

Materials and Methods

Reagents and instrumentation

Purolite Ltd., provided a variety of resins and adsorbents; their general properties are displayed in Table 3: 500 ppm stock solutions were prepared of Cs, Sr, Ce (III), Ce (IV) Co and Cu nitrate salts in 1% NO3- for batch uptake experiments; for the rate of uptake experiments, a Zr solution of 3,000 ppm in 2 M nitric acid was prepared.

Resin Name Functional Group Structure
100H Sulphonic Acid Gel Polystyrene with divinylbenzene at 8%
C100X10MBH Sulphonic Acid Gel Polystyrene with divinylbenzene at 10%
S910 Amidoxime Polyacryclic crosslinked with divinylbenzene
D5530 Unknown Unknown

Table 3: Adsorbents used and their functionality and polymeric properties.

All the reagents were of analar grade quality or equivalent with the exception of nitric acid, which was of trace metal analytical grade. The cation concentrations were determined using Thermo X-Series ICP-MS with Thermo PlasmaLab version 2.5.11.321. The deionised water which had a conductivity of 18.2 MΩ.cm used in these experiments was sourced from a Thermo Scientific Barnstead NANOPURE ion exchanger.

All equipment was routine standardised and appropriate standards used, in particular for ICP-MS determinations. Equilibration of cation solutions with the appropriate ion exchanger was accomplished using Julabo SW22 water bath set at the appropriate temperature and agitated at 200 rpm.

Batch uptake experiments

As the acid molar strength of the feed solution will be a determining and possible limiting factor on the separation of ions and efficiency of any chromatographic separation, batch studies of the effect of nitric acid strength (up to 4 M) on the uptake of ions by all adsorbents were initially investigated. Experiments were carried out in 250 ml Durran bottles with 100 ml of the required concentration of nitric acid; to this, a requisite amount of the cation stock solution was added to bring the cation concentration to 500 ppb. 1 g of the adsorbent was then added to the bottle, sealed and placed in the water bath and agitated at 25°C for 24 hours (24 hrs. taken to approximate equilibrium). Percentage uptake values were calculated and plotted against acid strength (Figures 2-4).

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Figure 2: Percentage uptake of various cations in nitric acid on C100H.

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Figure 3: Percentage uptake of various cations in nitric acid on S910.

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Figure 4: Percentage uptake of various cations in nitric acid on D5530.

Selectivity co-efficient at the same acid concentration were calculated by Equation 1:

image          (1)

The amount of each ion adsorbed per g of resin was calculated by Equation 2:

image          (2)

Where Co is the initial ion concentration (mgl-1), V the volume of nitric acid solution (l), m the weight of resin (g) and Ce the concentration at the end of the experiment taken as equilibrium (mgl-1).

Distribution coefficients were calculated from Equation 3:

image          (3)

Rate of cation uptake

Small samples were periodically withdrawn from the 3,000 ppm Zr/2 M nitric acid solution (100 ml) equilibrating at the appropriate temperature and subsequently analysed. It was considered that the Zr ions had reached equilibrium with exchange materials after 24 hours (Ce). Rates of Zr ion uptake as a function of time were calculated either as a percentage of Ce or Zr mass uptake (mg/g).

Results and Discussion

Capacity and selectivity

Selectivity and distribution coefficients were determined for six ions on three adsorbents with four ions being tested with the S910. Only one sulphonic acid resin graph is displayed as the similarity between the sulfonic C100H and C100x10 MBH resins, is differentiated only by the amount of divinyl benzene cross-linking agent within the resin structure (Figure 2). It is appreciated however that the degree of cross-linking does affect both capacity and selectivity of sulphonic acid ion exchange resins but in this study the affect and implications were marginal [14].

Uptake was observed for most of the cations over quite a large nitric acid molar range for the sulfonic resins, with the exception of cesium, the adsorption of which falls off quickly as the acidity is raised above 1.0 M.

At this acid concentration, the dissociation of sulphonic acid will be slightly impaired, and as the nitric acid concentration increases, the dissociation of SO3H will be further reduced in order to maintain the equilibrium, viz:

R- SO3H ↔ R-SO3-+H+ pKa of ~ -2.8 [15]

Ce and Zr ions are capable of overcoming this lack of dissociation by displacing the hydrogen ion attached to the functional group. As the measured maximum uptake for these ions is of the order 50 μg/g this would entail only 10-3% dissociation of the sulphonic acid group for a 1:1 SO3-Zr complex. The uptake of ions is higher for the more charged species, so zirconium (IV) is more retained than cerium (IV)>cerium (III)>strontium (II)>copper and cobalt (II)>caesium (I); this sequence is consistent with previously measured selectivities for sulphonic acid resins [16]. Cerium as reported earlier and zirconium ions are capable of forming nitrato- complexes in nitric acid which may assist in the uptake of these ions by the sulphonic acid functional group, in particular for monovalent species such as Ce(NO3)3+.

The acid concentrations for 50% extraction for Cs, Co, Cu, Sr, Ce (iii), Ce (iv) and Zr are 0.15, 0.4, 0.65, 1.40, 1.50 and 2.10 M respectively (Figure 2). These extraction profiles indicate that an effective separation of Cs, Co, Cu and Sr ions from Zr ions could be achieved in 2.0 M nitric acid, but the separation would be less efficient for Ce ions from Zr ions.

This separation factor trend for sulphonic acid resins is underpinned by the data reported in Tables 4 and 5. In 2 M acid, the separation factor for Cs ions from Zr ions is about 29 and nearly 20 and 16.4 for Co and Sr ions respectively for C100H. The performance of 100x MBH is slightly inferior with values of 22, ~ 10 and 6.5 respectively, which may be due to the higher degree of cross-linking.

Nitric Acid strength (M) Selective factor Equilibrium coefficient (Ked) Distribution coefficient (Kion) Retention factor (Kion)
  Co (II) Cu (II) Sr (II) Zr (IV) Cs (I) Ce (IV) Ce (III)
1 Co (II)   1.46 0.54 1101 2.07 104 1104 1516 0.16 1.58
1 Cu (II) 168 0.37 1101 1A2 1103 0.02 11172 0.11 1.08
1 Sr (II) 1.84 2.69 1102 180 1107 0.06 2910 0.29 2.90
1 Zr (IV) 102.04 14924 55.54 21129 4.08 160 1612.81 16.13 161.23
1 Cs (I) 1148 1171 126 0.11 1102 102 7.57 1108 1176
1 Ce (IV) 24.99 3654 13.60 1124 51/4 0.88 446.84 4.47 44.81
1 Ce (III) 28.37 41.49 15A4 1128 58/4 1.14 39429 3.94 39A8
2 Co (II) 1146 0.83 1102 1.48 0.08 1108 210 1103 1127
2 Cu (II) 2.19 1.81 105 123 1117 117 5.90 1106 159
2 Sr (II) 121 0.55 0.03 1.79 1109 109 327 1103 1133
2 Zr (IV) 4121 18.38 3326 59.43 114 105 108.32 1.08 11192
2 Cs (I) 1168 0.31 0.56 1102 0.05 0.05 1.83 0.02 1118
2 Ce (IV) 12.82 5.86 10.60 132 18.95 1197 35.38 0.71 L13
2 Ce (III) 13.20 613 10.92 1133 19.50 1.03 34.76 0.35 3.48
3 Co (II) 1153 1.02 1116 0.48 0.35 1148 196 0.04 0.40
3 Cu (II) 1.89 1.93 1131 0.90 0.66 1190 7.50 1108 0.75
3 Sr (II) 1198 0.52 1116 0.47 1134 1147 3.91 1104 0.39
3 Zr (IV) 6.17 327 620 2.96 2.14 2116 24.40 1124 245
3 Cs (1) 2.09 1.11 2.13 1134 0.72 1.00 2.90 1103 029
3 Ce (IV) 2.88 1.53 2.94 1147 1.38 1.38 824 108 1183
3 Ce (III) 2.09 1.11 2.13 1134 1.00 0.72 11A8 0.12 1.15

Table 4: Separation factors and distribution coefficients for C100H.

Nitric Acid Strength (M.) Selectivity Factor Equilibrium Coefficient (Kd) Ditribution Ratio (Kion) Retention Factor (Kion)
Co (II) Cu (II) Sr (II) Zr (IV) Cs (I) Ce (IV)
1 Co (II) - 1.04 0.35 01.01 1.57 0.02 25.86 0.26 2.58
1 Cu (II) 0.96 - 0.34 0.01 1.51 0.02 24.58 0.73 2.47
1 Sr (II) 2.83 2.95 - 0.02 4.46 0.06 72.61 29.46 7.30
1 Zr (IV) 114.36 119.37 40.42 - 180.09 2.26 2946.42 0.16 1.64
1 Cs (I) 0.63 0.66 0.22 0.01 - 0.01 16.30 4.49 44.81
1 Ce (IV) 50.51 5213 17.85 0.44 79.55 - 448.54 12.99 30.15
2 Co (II) - 010 0.64 0.03 1.39 0.07 8.48 0.09 0.85
2 Cu (II) 1.43 - 0.91 0.04 1.98 0.11 12.09 0.12 122
2 Sr (II) 1.56 1.09 - 0.04 2.16 0.12 1320 0.13 1.33
2 Zr (IV) 3971 27.82 25.45 - 55.07 2.95 33624 3.36 3319
2 Cs (I) 0.72 0.51 0.46 0.02 - 0.05 1135.81 11.36 113.85
2 Ce (IV) 13.48 9.44 8.64 0.34 18.69 - 12.63 2.45 24.70
3 Co (II) - 0.55 8 0.01 0.29 0.03 0.73 0.01 0.07
3 Cu (II) 1.81 - 8 0.02 0.52 0.06 1.32 0.01 0.13
3 Sr (II) 0.00 0.00 0.00 0.00 57.54 0.00 0.00 0.00
3 Zr (IV) 78.40 43.43 8 - 2217 2.74 57.54 0.58 516
3 Cs (I) 3.44 1.91 8 0.104 - 0.12 2.49 0.03 025
3 Ce (IV) 28.63 15.86 8 0.37 8.31 - 26.14 0.26 2.63

Table 5: Separation factors and distribution coefficients for C100X10MBH.

The difference in the sulfonic acid distribution coefficients is interesting; although they gave similar shaped graphs, the more highly cross-linked resin gave nearly double the distribution coefficient. This may be due to the interesting chemistry displayed by zirconium speciation at low acid concentrations (ZrO2+, Zr4+ and [Zr4(OH)8 (H20)16]8+). The variation in charges, hydrated radii and ionic diameters displayed at these low nitric acid concentrations will have a dramatic effect on the adsorption on to the resin. The pore size of the resin, density of active sites on its surface and capacity will all be limiting factors affecting uptake.

Large ions such as the [Zr4(OH)8(H2O)16]8+ will be less able to penetrate the internal structures and active sites within a resin than that of smaller ion such as ZrO2+ or Zr4+. It will also take more active sites on the resin to adsorb a 8+ charged hydrated ion than that of a 4+ or 2+ ion. This will effectively reduce the capacity of the resin for Zr. The relatively high cross-linking will reduce pore size within the resin, possibly making it too small for the hydrated ions, thus slowing the uptake. The ion does however behave as expected at the higher acid concentrations of most interest to this project, on both C100 resins.

The separation performance of the amidoxime resin for Zr ions from other cations is far superior to the sulphonic acid ion exchangers, for example at 50% extraction the acid concentrations are 0.1 and 0.2 M for Zr and Ce(iv) ions respectively (Figure 3). At these acid concentrations uptake of other cations is below 10%.

The distribution ratios recorded for Zr ions from 1 to 3M nitric acid solutions exceed 900 demonstrating the binding capacity of the amidoxime group (Tables 6 and 7).

Nitric Acid Selectivity Factor Equilibrium Coefficient (Kd) Distribution Ratio (Kion) Retention Factor (kion)
Strength (M) Co (II) Sr (II) Zr (IV) Cs (I) Ce (IV) Ce (III)
1 Co (II) 2.55 0.00 1.30 164 2.06 4.50 0.09 0.47
1 Sr (II) 0.39 0.00 0.51 25 0.81 0.64 0.01 0.06
1 Zr (IV) 1401.30 3571.12 1818.06 89129 2880.01 2258.14 22.58 226.22
1 Cs (I) 0.77 1.96 0.00 0.49 1.58 1.25 0.01 0.13
1 Ce (IV) 1.57 4.01 0.00 2.04 3.23 0.01 0.08
1 Ce (III) 0.49 1.24 0.00 0.63 131 2.53 0.03 0.25
2 Co (II) 8 0.01 8 8 8 12.32 0.25 1.26
2 Sr (II) 0.00 0.00 8 8 8 0.00 0.00 0.00
2 Zr (IV) 111.65 8 8 8 8 153162 15.31 153.40
2 Cs (I) 0.00 8 111.65 8 8 0.00 0.00 0.00
2 Ce (IV) 0.00 8 0.00 8 8 3.70 0.07 0.75
2 Ce (III) 0.00 8 0.00 8 8 4.44 0.00 0.00
3 Co (II) 0.76 0.01 72.92 2.83 2.71 31.29 0.63 3.16
3 Sr (II) 1.31 0.01 95.82 313 3.56 4155 0.81 4.11
3 Zr (IV) 196.73 149.72 14346.70 557.73 533.18 962.00 19.24 99.05
3 Cs (I) 0.01 0.01 0.00 0.014 0.04 1.89 0.04 0.19
3 Ce (IV) 0.35 0.27 0.00 2512 0.96 5.50 0.11 0.56
3 Ce (III) 0.37 0.28 0.00 26.91 1.05 0.96 0.02 0.10

Table 6: Separation factors and distribution coefficients for S910.

Cations Hydroxamic Acid Logß1 Logß2 Logß3 Logß4 Reference
U(vi) BHA 8.72 16.77      
U(iv) BHA 9.89 18.0   32.94 Barocas [22]
Pu(iv) BHA 12.73   26.32   Barocas [22]
Zr(iv) BHA 12.43 24.08     Baroncelli [21]
Fe(iii) AHA 11.42 21.10 28.33   Anderegg [23]
Fe(iii) BHA 12.18       Baroncelli [21]
Ce(iii) AHA 5.45 9.79 12.8   Anderegg [23]
La(iii) AHA 5.16 9.33 11.88   Anderegg [23]

Table 7: Stability constants for certain cations with BHA and AHA.

The reduction in uptake for the sulfonic resins can be described by the equilibrium between hydrogen ions on the resin, those in solution and the cation as previously explained. The S910 being a chelating resin is slightly different, it has the ability to complex with specific ions but reject others. The selectivity can be further enhanced by increasing acidity; this is demonstrated in the experiments where in deionised water the uptake of Ce (IV) ion is greater than that of Zr ion but is reduced close to zero once HNO3 is above 1 mol.l-1 [1].

In general hydroxamic acids are weak donors with the pKa values varying from 7.05 (nitrobenzohydroxamic acid) to 11.33 (N-phenyln- butylhydroxamic acid) [17]. amidoxime resins to remove cations from acid solutions has been reported on several previous occasions [18-20]. Vernon studied various transition metals such as Ni, Co, Cu, Pb V, Fe and U, Hg and Au in near neutral to acid solutions (pH values 6.0 to 1.0) and reported that V and Au had the highest capacities of ~ 0.8 mmoles/g and ~ 2.5 mmoles/g respectively at zero pH value [21]. The resin also had a high uptake for copper but at pH value of 6 (3.2 mmoles/g). This high capacity for copper ions is also a characteristic of S910 (40 g/l equivalent to ~ 0.5 mmoles/g) [14].

There are extensive reviews of the stability constants and metal complexation properties of hydroxamic acids but with emphasis on benzohydroxamic acid (BHA) complexes [22,23]. The metals of interest to UCLan’s chromatographic separation process that have been studied with BHA and AHA are Fe(iii), U(vi), Ru(iii), Zr(iv), Pu(vi) and rare earths [24].

The stability constants reported in Table 7 were measured in slightly acid to modest alkaline pH conditions i.e., ~ 2 to 10 unlike the nitric acid conditions employed in this study. Below pH values 1.0, the proportion of metal hydoxamate in solution will be small. This for most cations in our study is confirmed by the extraction-acid profiles in Figure 3, the exception is Zr ions. These profiles and the data in Table 7 would suggest that only mono-dentate or at worst bi-dentate ligands are formed.

The most interesting commercially available material supplied by Purolite Ltd., was D5530 that had strong uptake of cations from 1 to 3 M nitric acid (Figure 4). In 2 M, acid Zr ion was adsorbed totally with Cs, Sr, and Ce cations in the 60% region. At a higher acidity of 4M the separation was enhanced with Zr ion still at 100% uptake but the other cations with the exception of Cs reduced to around 20% uptake. Unfortunately an explanation of this trend cannot be provided, as the functionality of the material has not been disclosed.

The largest distribution coefficients for Zr ions were demonstrated by both the amidoxime chelate resin S910 and the inorganic D5530 (functionality not disclosed) (Table 8). The distribution coefficient is lower or remains similar as the nitric acid concentration increases for all ions tested, with the exception of Zr on the D5530 adsorbent. Some of the cation’s unpredictable uptake with varying acid concentration could be due to the formation of cation-nitrato complexes as already described for Ce and Zr ions; this could be equally true for the transition metals Cu and Co (Figure 4). This complex formation will also affect ion hydration influencing hydration size. A third contributory factor could be the potential for protonation of the D5530 functional group thus transforming the cation properties to anionic but this would require nitrato complexes of the type M(NO3)5. The latter is pure speculation as the precise nature, i.e., functional group of D5530 has not been declared. It would certainly be a challenge to configure a chromatographic separation process in a nitrate/nitric acid with D5530.

Nitric Acid Strength (M) Selectivity Factor Equilibrium Coefficient (Kd) Distribution Ratio (Kion) Retention Factor (Kion)
  Co (II) Sr (II) Zr (IV) Cs (I) Ce (IV)  
1 Co (II) - 1.07 0.62 0.1 3.44 1041 90.64 1.81 18.56
1 Cu (II) 0.93 - 0.58 0.09 3.22 0.38 84.41 1.69 17.34
1 Sr (II) 1.62 1.73 - 0.15 5.57 0.66 148.3 2.97 30.03
1 Zr (IV) 10.48 11.21 6.47 - 36.1 4.26 955.2 19.1 194.4
1 Cs (I) 0.29 0.31 0.18 0.03 - 0.12 155.6 3.11 31.34
1 Ce (IV) 2.46 2.63 1.52 0.23 8.47 - 78.52 0.79 7.87
2 Co (II) - 1.02 0.94 0.00 0.68 0.93 104.9 2.1 21.26
2 Cu (II) 0.98 - 0.92 0.00 0.67 0.91 103.8 2.08 20.92
2 Sr (II) 1.07 1.09 - 0.00 0.73 0.99 117.7 2.35 23.63
2 Zr (IV) 854.2 868.3 798.9 - 580 792.77 93737 1875 18920
2 Cs (I) 1.47 1.5 1.38 0.00 - 1.37 201.2 4.02 40.37
2 Ce (IV) 1.08 1.1 1.01 0.00 0.73 - 94.56 1.89 19.05

Table 8: Separation factors and distribution coefficients for D5530.

Rate of cation uptake

Understanding the kinetics of exchange of an ion exchange material in separation technology, helps in identifying the reaction pathway and rate dependence on the limiting reacting systems. These rates and mechanisms are influenced by for example ion exchange conditions, nature of the exchanger and exchanging ionic species. Ion exchange kinetics involves the diffusion of metal ions through the solution to the surface and through the particle pores of the resin followed generally by the chemical exchange between functional hydrogen ions and metal ions at the exchanging sites and the diffusion of the displaced ions out of the interior and surface of resin into the solution. Both film and particle diffusion mechanisms are prevalent in ion exchange process, although normally the slowest step (rate-limiting step) for a given system controls the speed of ion exchange.

The equilibration rate of four selected exchangers was studied using Zr (iv) ions only as it is the only cation to display any significant uptake on each of the adsorbents evaluated in nitric acid conditions.

The rate factor in ion-exchange adsorption is recognized for its importance for the economic and industrial employment of ion-exchange resins, no more so than the application under consideration. The kinetic data reported in Figures 5-7, show all four resins increased Zr ion uptake with time reaching near 100% after several hours for most resins but with the amidoxime resin having a more rapid uptake initially. At the 300 min. time interval the amidoxime (S910) is the more superior resin with the other three having similar rates. This is unexpected as S910 is a chelating resin and it would be expected that formation of complexes would be slower than simple salt formation, as would be expected with sulphonic acid resins. This irregular behaviour may be due to either the resin porosities being affected differently when in contact with 2 M nitric acid and/or the sulphonic acid resins forming more complex binding to the Zr4+ ions than a simple salt formation, i.e., the incorporation of nitrate ion to achieve electron neutrality.

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Figure 5: Mass uptake of Zr (iv) on four adsorbents and resins at 25°C.

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Figure 6: Mass uptake of Zr (iv) on four adsorbents and resins at 45°C.

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Figure 7: Mass uptake of Zr (iv) on four adsorbents and resins at 65°C.

The largest increase in the uptake rate observed over the temperature range 25 to 45°C is for that of the inorganic D5530 whilst the S910 resin is the least affected by the change in temperature. This however may be due to the capacity of the resin for the ion and the initial ion concentration of the liquor driving a concentration gradient effect: essentially meaning that temperature is not the most important factor in the uptake of the Zr ion for the amidoxime resin. However, this is not borne out when compared to the uptake on the inorganic D5530, which has a similar uptake, which shows a distinct increase in uptake as temperature is increased. At temperatures greater than 45°C for both the amidoxime and inorganic exchanger, the Zr ion uptake values decreased. This could be attributed to the oxidation/degradation of the functional groups. The stability of these four resins is addressed in the next paper of this series.

The difference in the two sulfonic resins is less pronounced than that of the D5530, but does still display a slight increase with temperature.

The increase in uptake rate and capacity with the increase in the temperature of the system is well described in many articles and is expected for both the sulfonic acid resin and amidoxime [25,26].

The increase in uptake related to the temperature increase may be due to the exchange reaction, i.e., being endothermic. Additionally the increase in temperature might cause the electrostatic reactions to become weaker and subsequently the ions to become smaller with a decreased ion solvency within the HNO3 liquor and an increase in the diffusion coefficients through both the film coating the bead and through the resin make up. This will in turn produce a higher exchange velocity between the solution and the resin [27].

In order to elucidate the mechanisms taking place, the degree of extraction [ln (1-α)] of Zr ions from solution was plotted against time to derive the rate constant; where α is defined as:

image           (4)

Where: Co is the initial concentration of metal ion in solution (mg/l), Ct is the concentration of metal ion in solution at any time, t (mg/l), Ce is the concentration of the metal ion at equilibrium (mg/l), and α is the fractional attainment of equilibrium of metal ion.

The rate constant k can be derived from:

ln (1-α)=-kt           (5)

and the activation energy Ea calculated using:

image          (6)

Where, A is the pre exponential factor, R is the gas constant, and T is temperature.

The plots of ln (1-α) versus time (not shown) at different temperatures were linear confirming that the ion exchange process is particle diffusion controlled. The value of the overall rate constant, k was deduced from the slope of the plots. This was substantiated by comparing the coefficient of determination (R2) measurements from the ln (1-α) and ln (1-α2) plots for the Vermeulen particle and film diffusion models (Equations 7 and 8).

image          (7)

image            (8)

Where, Dp is the diffusion coefficient in the ion exchanger (m2/sec), rp is the radius of the particle (m), Df is the diffusion coefficient in the film (m2/sec), Co and Ce are concentrations in the solution and in the exchanger respectively (mol/m3), δ is the film thickness.

Although coefficient of determination values from the two plots at 25°C for the four exchange materials studied were close (more so for the sulphonic acid resins) suggesting an interplay of film and particle diffusion in the exchange process the best fits for all four were with the Vermeulen’s particle diffusion model which exhibited higher values of coefficient determination (Table 8).

These values indicate that the rate controlling mechanism for the exchange reaction is particle diffusion. The activation energy values predicted using equation 6 are 20.25, 20.87, 18.25 and 18.02 kJ/mole for C100H, C100X10MBH, S910 and D5530 respectively. These values suggest that the mechanism is one of ion exchange of the Zr ions with hydrogen ions on the sulphonic acid exchange materials, but for D5530 physisorption could also be playing a part and complexation for the S910 (Tables 9 and 10).

Temperature (°C) Zr (IV) Ion Exchange Capacity (mgg-1)
25 45 60
Resin   +/-   +/-   +/-
C100H 14.6 0 17 0.4 19.8 0.9
C100 × 10MBH 14.0 1.3 18.4 1.7 19.0 0
SN10 4.7 1.7 4.6 0.6 2.4 0.7
D5530 2.4 1.2 6.1 0.5 4.2 0.2

Table 9: Mass of Zr ion uptake on different adsorbents at differing temperatures.

Equation Ion exchange material coefficients of determination
C100H C100x10MBH S910 D5530
-ln(1-a)2 0.9914 0.9917 0.9827 0.9482
-ln(1-a) 0.9426 0.9769 0.8777 0.9385

Table 10: Comparison of coefficients of determination (R2) for the Vermeulen particle and diffusion models for Zr ions at 25°C.

Conclusions

Of the four ion exchange materials reported in this paper the sulphonic acid resins offer little opportunity for chromatographic separation of Cs and/or Sr from other fission products when in nitric acid solutions of 1 to 3 M concentration. The data reported suggest it is the converse, i.e., Zr could be extracted from these two fission products with either the sulphonic acid resins or the amidoxime resin.

The rate of extraction of Zr ions from 2 M nitric acid solution is modest i.e., less than 24 hrs to attain equilibrium for the sulphonic acid resins, much quicker for the amidoxime resin.

There was an indication that the exchange materials under investigation in nitric acid solutions at ambient temperature could be undergoing oxidative/hydrolytic damage which was exacerbated at higher temperatures. The stability of these materials is the subject of another paper.

The kinetic data confirms that the rate controlling uptake step for Zr ions is particle diffusion and the mechanism is one of ion exchange for all four materials, the predicted Ea values were similar (~ 20 kJ/ mole). The inorganic exchanger (D5530) had the lowest Ea value (18.02 kJ/mole) which infers that ion exchange could be supplemented by physisorption; with complexation dominating the mechanism for the amidoxime resin (S910).

The separation factors recorded for the four materials were sufficiently encouraging for column studies and chromatographic separations to be undertaken. This is the subject of further publications.

Acknowledgements

The authors would like to thank Purolite Ltd (Unit D, Llantrisant Business Park, Llantrisant, Rhondda Cynon Taff, Wales, United Kingdom CF72 8LF) for the provision of ion exchange materials and technical support and to the NNL (National Nuclear Laboratory, Central Laboratory, Sellafield, Seascale, Cumbria CA20 1PG), for technical contributions. JDE’s Ind CASE award was funded by both the NNL and EPSRC (EP 1501312/1), the authors are grateful for this support.

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Author Info

Gary Bond, Harry Eccles* and John D Emmott
 
School of Physical Sciences and Computing, University of Central Lancashire, Preston PR1 2HE, UK
 

Citation: Bond G, Eccles H, Emmott JD (2019) Separation of Cations from Nitric Acid Solutions Using Commercially Available Ion Exchange Resins. J Chem Eng Process Technol 9: 393. doi: 10.35248/2157-7048.19.10.393

Received: 26-Nov-2018 Accepted: 20-Mar-2019 Published: 25-Mar-2019 , DOI: 10.35248/2157-7048.19.10.393

Copyright: © 2019 Bond G, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.